EXERCISE - CHEMICAL INDUSTRY: NETCAR


1.- OBJECTIVE

The purpose of the exercise is to study the alternatives whereby a company that specialises in the cleaning of chemical tankers (tanker truck wash) can:

- Reduce its water consumption.
- Comply with the waste water dumping regulations.
- Minimise investment in the on-site waste water treatment plant.

The company in question is the NETCAR Company in the chemical industry.

The particular issues here are:
  1. What actions can be carried out to reduce the total water consumption and waste water that is generated by the company?
2. What will water consumption and waste water generation (volumes) be after the proposed alternatives have been put into practice?



2.- AVAILABLE DATA

The basic data for this exercise include:

- A general description of the Company.
- Description of the plant facilities.
- Water consumption.
- Characteristics of the waste water produced.
- Number and description of waste flows generated. The causes of waste flow generation. Current management practice.



2.1.- GENERAL DESCRIPTION OF THE COMPANY

The NETCAR company uses a cleaning system that has a very high water consumption and produces a large quantity of waste water (with a high overall pollutant load).

Although these problems are very common in many enterprises and industrial sectors, this exercise focuses on one specific case:

A facility for cleaning tanker trucks that transport chemical products (here referred to chemical tanker truck wash facilities).
International regulations covering the transportation and loading and unloading of chemicals require the inside of tankers to be totally cleaned out once they have unloaded the chemicals being transported to eliminate all chemical remains.

Water consumption in chemical tanker truck wash facilities is very high, as is the amount of waste water that is produced (practically the same as consumption). Pollutant load is also very high. This means a large investment by the NETCAR company in an on-site treatment plant.

Tanker lorries that come to the facilities also generally have the outside and underside of the vehicle cleaned as well.

The activities of the NETCAR company are undergoing expansion and there is a big increase in the number of tankers being cleaned, which means that the treatment plant cannot comply with set limits for the dumping parameters of waste water due to the excess volume of water being treated.




2.2.- DESCRIPTION OF THE PLANT FACILITIES

Tanker truck inside wash units

This has a dual structure with a series of connections that fits onto the tanker man-holes by way of a plate; a set of satellite nozzles underneath the plate spins at high speed from the water under high pressure.

Following a preliminary hose-down and a visual check of the inside of the tank, a set of very high pressure pumps (100 to 200 bar) injects water through pipes to each plate and set of satellite nozzles that cleans the inside walls of the tank. The water that is injected at high pressure may contain detergent and also be hot (the water is heated in a boiler with a gas-oil burner).

There are two cleaning units which means that two tankers can be cleaned at the same time, while two more are being prepared to be washed.

Vaporisation is also carried out in the internal wash unit area. This uses steam from a boiler with a gas-oil burner.

Dirty wash water falls to the ground and is collected in channels leading to the waste water treatment plant.

The preliminary hose-down consumes 20% of the volume of water used in inside cleaning.

Tanker truck outside body wash unit

This is a tanker truck outside body wash facility that is especially for extra-long tankers and is similar (although larger) to regular car washes.

Together with the cleaning brushes and sections for drenching, detergent wash and end rinse, the facility has a water decalcifying unit for the end rinse. High pressure hoses are installed in the truck wash.

Dirty wash water falls to the ground and collects in a separating sump. From here, it is pumped to the waste water treatment plant, mixed together with the water from the inside wash.

Waste water treatment plant

Waste water from both the inside and outside washes is collected in a separating sump.

From here, it is pumped to a degreasing plant (which works by flotation) by a bubble cavitation system. The grease and hydrocarbons are dragged to the surface by the air bubbles to form a creamy mass that is collected by cable-operated blades that carry the grease to a container, where an authorised waste manager collects the waste.

The degreased water gathers in a large vented homogenisation tank with a 16-hour waste water production capacity.

The water is pumped from the homogenisation tank at a constant flow to the following sections of the treatment plant.

The first section involves a physiochemical treatment where a coagulation process takes place, followed by flocculation. An automatic pH control is installed (generally involving the use of caustic soda) to ensure the system operates correctly (most of the waste water is acidic).

The water from the physiochemical treatment is pumped to a separation sump. The clarified water overflows and flows by gravity feed to the biological reactor. The sludge collected (by time delay) from the bottom of the separation sump is pumped to a sludge thickener.

The biological reactor has fine bubble membrane diffusers with an outside blower system. The most important part of the waste water treatment process takes place in the reactor. The mixture of biological sludge and purified water goes into a separating tank. The separated water goes into a sump and can then be dumped directly into the sewerage system or can be passed through a filtration system. The separated sludge at the bottom of the separation sump is recycled to the biological reactor and part of it (more or less depending on the biological control of the active sludge in the reactor) is drained off and processed in the sludge thickener (the same sludge thickener as in the physiochemical process).

The final filtration system consists of a semi-automatic silex and anthracite filter, which is only used where necessary. The final filtration process is not necessary when the biological treatment is working correctly and the biological sludge separates out well.

Excess water from the sludge thickener returns by gravity feed to the homogenisation tank. Thickened sludge (more from the physiochemical process than the biological treatment) are mixed with lime wash (prepared in a tank with agitator) and are pumped to the dehydration system.

Dehydration of the sludge is carried out using a filter press, in which the sludge is passed through rack-mounted gauzes under high pressure. The pressure exerted by the plates that the gauzes are attached to press dries and dehydrates the sludge (now filter cake), which falls into a container where an authorised waste manager can collect it.
Water drained from the filter press is pumped to the homogenisation tank.

The diagram below shows how the water is purified:



2.3.- WATER COMSUMPTION

Water consumption is highly irregular. Consumption only occurs during working hours in the truck washes.

The tanker truck inside wash units consume large quantities of water when water is being injected under high pressure.

Estimated flow in this facility is (average daily volume):

- Tanker truck inside washing: 100m³ / day
- Tanker truck outside body wash: 20m³ / day


2.4.- CHARACTERISTICS OF THE WASTE WATER PRODUCED

The pollutant load of the waste water produced in tanker truck inside washing is highly variable, depending on the products that have been transported in the tanks and also how much they have been emptied (i.e. the amount of product that remains inside the tanker when it reaches the inside wash unit).

For this reason, a very large homogenisation tank is necessary (in order to homogenise as much as possible the quality of the waste water to be treated in the treatment plant). It also underlines the importance of the physiochemical system, which serves to pretreat and protect the following biological treatment.

The established limits set by the local municipal authorities for the parameters of the pollutant load dumped into the sewerage system are relatively low and the quality of the treated water that is dumped is acceptable when the treatment plant is working correctly.

Waste water produced in the tanker truck outside body wash facility contains practically nothing more than earth and dirt, together with a little grease, although the pollutant load is very low (except for it being very cloudy as a result of suspended matter).


3.- APPROACH

  The issue here is to find possible alternative ways to recycle and segregate the types of waste water. A circuit needs to be designed for the water that takes account of the rate of pollutant load from the activities described above [tank cleaning and vehicle cleaning].

Up to 50% of the outside body wash water can be recycled with the appropriate modifications (redesign).
With the correct management of water, only 10% of the water from the outside body wash facility should have to go to the treatment plant.

From the description of the processes and the data provided:
    - Identify actions that can be carried out to reduce the company's total water consumption and the amount of waste water that is generated.
- Calculate the water consumption and the amount of waste water generated after the proposed alternatives have been applied.




4.- ANSWER TO THE EXERCISE

1. Minimisation actions:

A critical analysis of the Company's water requirements
- The preliminary hose-down inside the tanks requires clarified water although it is not necessary to consume mains water, as is done at the present time.

- Likewise, the prewash water used in the outside body wash unit does not need to be pure mains water. Clarified water with no dissolved pollutant load is sufficient.

- Waste water produced in the outside body wash facility is all treated in the treatment plant although neither the physiochemical treatment nor the biological treatment are necessary as long as this water is not mixed together with water from inside washing (which is highly polluted).
Proposal to modify the cleaning system and to use water with different qualities.
- Inside wash

Certain changes of operation are proposed, together with the use of different quality water:
    • Segregate the wash water containing residual product from the tanker when it arrives at the wash facility and store in containers or drums. This is to be managed as waste through an authorised waste manager. This will lead to a big decrease in the pollutant load of the water sent to the treatment plant.

• The preliminary low pressure hose-down could be done using output water from the treatment plant. This water is clarified and although it contains a moderate level of dissolved contamination, it could be used for the first rough wash-down of the tank. A 20% saving of water consumption can be achieved with this action in the inside wash facility.

• For very high pressure cleaning, the proposal is made to continue using mains water, given that the equipment is sensitive.
  - Outside wash

Waste water segregation and the reuse of water are the proposals made here:
  • The waste water produced in this facility practically only contains suspended matter although there is very little dissolved pollution. It does not make sense to mix this with highly contaminated water from inside washes or water that needs to be treated in the physiochemical system or biological treatment process.

• Given that these waste waters enter a separating tank first and are then pumped to the treatment plant, the proposal is made to replumb the system and to pump them directly to the sand and anthracite filter which is currently under-used. Filtered water is recycled and can be entirely used for outside washing of the tankers. To prevent the concentration of dissolved grime, part (10%) of this water is drained off and sent to the treatment plant.

• Rinsing is done with mains water while decalcified water is used for the final rinse.

• A 50% saving of water consumption can be achieved with these actions in the outside wash facility.

2. Calculating the water consumption and the quantity of waste water generation after the proposed alternatives are put into practice.

Quantifying the savings

Water conservation in the inside wash facility: 20% * 100m³/h = 20m³/h
Water conservation in the outside wash facility: 50% * 20m³/h = 10m³/h

TOTAL WATER CONSERVATION: 30m³/h

(Initial water consumption following minimisation and with no consideration of recycling: 90m³/h)
Waste water treated in the treatment plant:

From inside washes (1): 100 - 20 = 80m³/h
From outside washes (2): 10% * 10 = 1m³/h

TOTAL WATER TREATED IN THE TREATMENT PLANT: 81m³/h

Calculations:

Final water consumption:
80m³/h + 1m³/h* = 81m³/h (*9 m³/h remaining are recycled)

(1) This waste water will have a lower pollutant load, which at the outset is non-quantifiable due to segregation of the tanker rinses.
(2) Only the part drained off of the water recycling circuit, which is estimated at being 10% of consumption, would go to the treatment plant


3. Conclusions:

Through these action, 33% of the capacity of the treatment plant would be opened up, or in other words, tanker cleaning activity could be increased by 33% without the need for any investment in enlarging the treatment plant, with a water consumption that is lower than initially.

Furthermore, these actions guarantee that, despite an increase in activity, the treatment plant will continue to comply with the limits established for discharged pollutant load.